In-situ continuous hydrothermal synthesis of TiO2 nanoparticles on conductive N-doped MXene nanosheets for binder-free Li-ion battery anodes

Journal article


Alli, U., McCarthy, K, Baragau, I., Power, N., Morgan, K, Dunn, S., Killian, S, Kennedy, T. and Kellici, S. (2021). In-situ continuous hydrothermal synthesis of TiO2 nanoparticles on conductive N-doped MXene nanosheets for binder-free Li-ion battery anodes. Chemical Engineering Journal. https://doi.org/10.1016/j.cej.2021.132976
AuthorsAlli, U., McCarthy, K, Baragau, I., Power, N., Morgan, K, Dunn, S., Killian, S, Kennedy, T. and Kellici, S.
Abstract

Anode materials are key to determining the energy density, cyclability and of life recyclability for Li-ion energy storage systems. High surface area materials, such as MXenes, can be manufactured with improved electrochemical properties that remove the need for polymeric binders or hazardous chemicals that pose a challenge to recycle Li-ion batteries. However, there remains a challenge to produce Li-ion anode materials that are binder free and poses energy storage characteristics that match the current carbon-based electrodes. Here we show the synthesis of N-doped MXene-TiO2 hybrid anode materials using an aqueous route. N-doped TiO2-MXene was modified using a single step continuous hydrothermal process. Capacity tests indicate an improvement from the initial specific energy capacity of 305 mAhg-1 to 369 mAhg-1 after 100 cycles at a charge rate of 0.1 C and a Coulombic efficiency of 99.7%. This compares to 252 mAhg-1 for the unmodified MXene which exhibited significant capacity fade to 140 mAhg-1. The ability to manufacture a Li-ion anode that does not require toxic chemicals for processing into an electrode and exhibits good energy storage characteristics in a binder free system is a significant step forward for energy storage applications.

KeywordsMXene; nitrogen-doping; continuous hydrothermal flow synthesis; binder-free electrode processing.
Year2021
JournalChemical Engineering Journal
PublisherElsevier
ISSN1385-8947
Digital Object Identifier (DOI)https://doi.org/10.1016/j.cej.2021.132976
Web address (URL)https://www.sciencedirect.com/science/article/pii/S1385894721045526#!
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Print14 Oct 2021
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Accepted09 Oct 2021
Deposited15 Oct 2021
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Fabbiyola, S, Kennedy, L J, JudithVijaya, J, Bououdina, M and Dunn, S (2016). Structural, Optical and Magnetic Properties of Cu-Doped ZnO Nanoparticles by Co-Precipitation Method. Journal of Nanoscience and Nanotechnology. 16 (9), pp. 9722-9730. https://doi.org/10.1166/jnn.2016.12094
Imaging the continuous hydrothermal flow synthesis of nanoparticulate CeO2 at different supercritical water temperatures using in situ angle-dispersive diffraction
Middelkoop, V, Tighe, CJ, Kellici, S, Gruar, RI, Perkins, JM, Jacques, SDM, Barnes, P and Darr, JA (2014). Imaging the continuous hydrothermal flow synthesis of nanoparticulate CeO2 at different supercritical water temperatures using in situ angle-dispersive diffraction. Journal of Supercritical Fluids. 87, pp. 118 - 128. https://doi.org/10.1016/j.supflu.2013.12.022
Optical and photocatalytic behaviours of nanoparticles in the Ti-Zn-O binary system
Goodall, JBM, Kellici, S, Illsley, D, Lines, R, Knowles, JC and Darr, JA (2014). Optical and photocatalytic behaviours of nanoparticles in the Ti-Zn-O binary system. RSC Advances. 4 (60), pp. 31799 - 31809. https://doi.org/10.1039/c3ra48030e
Acoustic enhancement of polymer/ZnO nanorod photovoltaic device performance
Shoaee, S, Briscoe, J, Durrant, JR and Dunn, S (2013). Acoustic enhancement of polymer/ZnO nanorod photovoltaic device performance. Advanced Materials. 26 (2), pp. 263-268. https://doi.org/10.1002/adma.201303304