Calixarene Assisted Rapid Synthesis of Silver-Graphene Nanocomposites with Enhanced Antibacterial Activity

Journal article


Kellici, S, Acord, J, Vaughn, A, Power, N, Morgan, D, Heil, T, Facq, S and Lampronti, G (2016). Calixarene Assisted Rapid Synthesis of Silver-Graphene Nanocomposites with Enhanced Antibacterial Activity. ACS applied materials & interfaces. 8 (29), pp. 19038-19046. https://doi.org/10.1021/acsami.6b06052
AuthorsKellici, S, Acord, J, Vaughn, A, Power, N, Morgan, D, Heil, T, Facq, S and Lampronti, G
Abstract

Demonstrated herein is a single rapid approach employed for synthesis of Ag graphene nanocomposites, with excellent antibacterial properties and low cytotoxicity, by utilizing a Continuous Hydrothermal Flow Synthesis (CHFS) process in combination with phexasulfonic acid calix[6]arene (SCX6) as an effective particle stabilizer. The nanocomposites showed high activity against E. coli (Gram-negative) and S. aureus (Gram-positive) bacteria. The materials were characterized using a range of techniques including transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, UV-Vis spectrophotometry, FT-IR and X-ray powder diffraction (XRD). This rapid, single step synthetic approach not only provides a facile means of enabling and controlling graphene reduction (under alkaline conditions), but also offers an optimal route for homogeneously producing and depositing highly crystalline Ag nanostructures into reduced graphene oxide substrate.

Keywordsgraphene; silver; nanocomposite; antibacterial; calixarene; hydrothermal
Year2016
JournalACS applied materials & interfaces
Journal citation8 (29), pp. 19038-19046
PublisherAmerican Chemical Society (ACS)
ISSN1944-8244
Digital Object Identifier (DOI)https://doi.org/10.1021/acsami.6b06052
Publication dates
Print05 Jul 2016
Publication process dates
Deposited30 Aug 2016
Accepted05 Jul 2016
Accepted author manuscript
License
File Access Level
Open
Supplemental file
License
File Access Level
Open
Additional information

This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for
publication in ACS Applied Materials and Interfaces, copyright © American Chemical Society after peer review. To access the final edited and published work see http://dx.doi.org/10.1021/acsami.6b06052

Permalink -

https://openresearch.lsbu.ac.uk/item/87355

Download files


Accepted author manuscript

Supplemental file
esi 24TH JUNE.pdf
License: CC BY 4.0
File access level: Open

  • 130
    total views
  • 316
    total downloads
  • 2
    views this month
  • 47
    downloads this month

Export as

Related outputs

Enhancing physicochemical properties of coconut oil for the application of engine lubrication
Hettiarachchi, S., Kellici, S., Kershaw, M and Bowen, D.J. (2023). Enhancing physicochemical properties of coconut oil for the application of engine lubrication. Tribology International . 190, p. 109060. https://doi.org/10.1016/j.triboint.2023.109060
Nanostructured Al2O3/Graphene Additive in Bio-Based Lubricant: A Novel Approach to Improve Engine Performance
Hettiarachchi, S., Bowen, D.J., Kershaw, M, Baragau, I., Nicolaev, A and Kellici, S. (2023). Nanostructured Al2O3/Graphene Additive in Bio-Based Lubricant: A Novel Approach to Improve Engine Performance. Tribology International . 186, p. 108619. https://doi.org/10.1016/j.triboint.2023.108619
Outstanding visible light photocatalysis by nano-TiO2 hybrids with nitrogen-doped carbon quantum dots and/or reduced graphene oxide
Baragau, I., Buckeridge, J., Nguyen, K., Heil, T, Sajjad, T., Thomson, S., Rennie, A., Morgan, D., Power, N., Nicolae, S., Titirici, M., Dunn, S. and Kellici, S. (2023). Outstanding visible light photocatalysis by nano-TiO2 hybrids with nitrogen-doped carbon quantum dots and/or reduced graphene oxide. Journal of Materials Chemistry A. https://doi.org/10.1039/D2TA09586F
3D printed SrNbO2N photocatalyst for degradation of organic pollutants in water
Iborra-Torres, A., Husˇ, M., Nguyen, K., Vamvakeros, A., Sajjad, T., Dunn, S., Mertens, M., Jacques, S., Beale, A., Likozar, B., Hyett, G., Kellici, S. and Middelkoop, V. (2023). 3D printed SrNbO2N photocatalyst for degradation of organic pollutants in water. Materials Advances. https://doi.org/10.1039/D2MA01076C
Investigating the effect of N-doping on carbon quantum dots structure, optical properties and metal ion screening.
Nguyen, K.G., Baragau, I-A., Gromicova, R., Nicolaev, A., Thomson, S. A J, Rennie, A., Power, N. P, Sajjad, T. and Kellici, S. (2022). Investigating the effect of N-doping on carbon quantum dots structure, optical properties and metal ion screening. Scientific Reports. 12 (1), p. 13806. https://doi.org/10.1038/s41598-022-16893-x
In-situ continuous hydrothermal synthesis of TiO2 nanoparticles on conductive N-doped MXene nanosheets for binder-free Li-ion battery anodes
Alli, U., McCarthy, K, Baragau, I., Power, N., Morgan, K, Dunn, S., Killian, S, Kennedy, T. and Kellici, S. (2021). In-situ continuous hydrothermal synthesis of TiO2 nanoparticles on conductive N-doped MXene nanosheets for binder-free Li-ion battery anodes. Chemical Engineering Journal. https://doi.org/10.1016/j.cej.2021.132976
3D printed catalytic reactors for aerobic selective oxidation of benzyl alcohol into benzaldehyde in continuous multiphase flow
Jacquot, C., Middelkoop, V., Köckritz, A., Pohar, A., Bienert, R., Kellici, S., Bărăgău, I.A., Venezia, B., Gavriilidis, A., Likozar, B. and Beale, A.M. (2021). 3D printed catalytic reactors for aerobic selective oxidation of benzyl alcohol into benzaldehyde in continuous multiphase flow. Sustainable Materials and Technologies. https://doi.org/10.1016/j.susmat.2021.e00329
An Efficient Continuous Hydrothermal Flow Synthesis of Carbon Quantum Dots from a Targeted Biomass Precursor for On-Off Metal Ions Nano-Sensing
Baragau, I., Power, N., Morgan, D, Lobo, R, Roberts, C, Titirici, M., Dunn, S. and Kellici, S. (2021). An Efficient Continuous Hydrothermal Flow Synthesis of Carbon Quantum Dots from a Targeted Biomass Precursor for On-Off Metal Ions Nano-Sensing. ACS Sustainable Chemistry & Engineering. 9 (6), pp. 2559-2569. https://doi.org/10.1021/acssuschemeng.0c08594
Continuous Hydrothermal Flow Synthesis of S-Functionalised Carbon Quantum Dots for Enhanced Oil Recovery
Baragau, I., Lu, Z., Power, P.N., Morgan, J.D, Bowen, J., Diaz, P. and Kellici, S. (2020). Continuous Hydrothermal Flow Synthesis of S-Functionalised Carbon Quantum Dots for Enhanced Oil Recovery. Chemical Engineering Journal. 405, p. 126631. https://doi.org/10.1016/j.cej.2020.126631
Continuous Hydrothermal Flow Synthesis of Blue-Luminescent Carbon Quantum Dots as Nanosensors for Chromium (VI) Detection
Baragau, I. and Kellici, S. (2020). Continuous Hydrothermal Flow Synthesis of Blue-Luminescent Carbon Quantum Dots as Nanosensors for Chromium (VI) Detection. London Doctoral Academy Postgraduate Research Summer School 2020. Online 06 - 09 Jul 2020 London South Bank University.
Enhancing engine oil performance using nanoparticles and bio-lubricants as additives
Hettiarachchi, S. J., Kellici, S. and Bowen, D.J. (2020). Enhancing engine oil performance using nanoparticles and bio-lubricants as additives. London Doctoral Academy Postgraduate Research Summer School 2020. Online 06 - 09 Jul 2020 London South Bank University.
CHFS of MXene Derivatives for Electrochemical Energy Storage
Alli, U. and Kellici, S. (2020). CHFS of MXene Derivatives for Electrochemical Energy Storage. London Doctoral Academy Postgraduate Research Summer School 2020. Online 06 - 09 Jul 2020 London South Bank University.
Continuous flow vortex fluidic-mediated exfoliation and fragmentation of two-dimensional MXene
Mohammed Al-antaki, A, Kellici, S., Power, P .N., Lawrance, W and Raston, C (2020). Continuous flow vortex fluidic-mediated exfoliation and fragmentation of two-dimensional MXene. Royal Society Open Science. 7 (5), p. 192255. https://doi.org/10.1098/rsos.192255
Chemical functionalisation of 2D materials via batch and continuous hydrothermal flow synthesis
Alli, U., Hettiarachchi, S. and Kellici, S. (2020). Chemical functionalisation of 2D materials via batch and continuous hydrothermal flow synthesis. Chemistry–A European Journal. https://doi.org/10.1002/chem.202000383
Vortex fluidic mediated synthesis of TiO2 nanoparticle/MXene composites
Al-antaki, A., Alharbi, T, Kellici, S., Power, N., Lawrance, W. and Raston, C. (2020). Vortex fluidic mediated synthesis of TiO2 nanoparticle/MXene composites. ChemNanoMat. https://doi.org/10.1002/cnma.201900779
Continuous Hydrothermal Flow Synthesis of Blue-Luminescent, Excitation-Independent Nitrogen-Doped Carbon Quantum Dots as Nanosensors
Baragau, I., Power, N., Morgan, D., Heil, T., Lobo, R., Roberts, C., Titirici, M.M., Dunn, S. and Kellici, S. (2020). Continuous Hydrothermal Flow Synthesis of Blue-Luminescent, Excitation-Independent Nitrogen-Doped Carbon Quantum Dots as Nanosensors. Journal of Materials Chemistry A. (8), pp. 3270-3279. https://doi.org/10.1039/C9TA11781D
Hydrothermal flow for 2D materials
Kellici, S. (2019). Hydrothermal flow for 2D materials. Materials World. September (2019), p. 42.
Next frontiers in cleaner synthesis: 3D printed graphene-supported CeZrLa mixed-oxide nanocatalyst for CO2 utilisation and direct propylene carbonate production
Middelkoop, V, Slater, T, Florea, M, Neațu, F, Danaci, S, Onyenkeadi, V, Boonen, K, Saha, B., Baragau, I. and Kellici, S (2019). Next frontiers in cleaner synthesis: 3D printed graphene-supported CeZrLa mixed-oxide nanocatalyst for CO2 utilisation and direct propylene carbonate production. Journal of Cleaner Production. 214, pp. 606-614. https://doi.org/10.1016/j.jclepro.2018.12.274
Greener synthesis of dimethyl carbonate using a novel tin-zirconia/graphene nanocomposite catalyst
Saada, R, Aboelazayem, O, Kellici, S, Heil, T, Morgan, D, Lampronti, G and Saha, B (2018). Greener synthesis of dimethyl carbonate using a novel tin-zirconia/graphene nanocomposite catalyst. Applied Catalysis B: Environmental. 226, pp. 451-462. https://doi.org/10.1016/j.apcatb.2017.12.081
Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts
Onyenkeadi, V, Aboelazayem, O, Kellici, S and Saha, B (2018). Greener synthesis of butylene carbonate via CO2 utilisation using graphene-inorganic nanocomposite catalysts. GPE 2018 – 6th International Congress on Green Process Engineering. Toulouse, France 03 - 06 Jun 2018
Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst
Onyenkeadi, V, Kellici, S and Saha, B (2018). Greener synthesis of 1,2-butylene carbonate from CO2 using graphene-inorganic nanocomposite catalyst. Energy. 165, pp. 867-876. https://doi.org/10.1016/j.energy.2018.09.135
Continuous Hydrothermal Flow Synthesis of Graphene Quantum Dots
Kellici, S, Acord, J, Power, N, Morgan, D, Heil, T, Coppo, P, Middelkoop, V, Baragau, I., Moore, K and Raston, C (2018). Continuous Hydrothermal Flow Synthesis of Graphene Quantum Dots. Reaction Chemistry and Engineering. 6. https://doi.org/10.1039/C8RE00158H
Green Process Engineering as the Key to Future Processes
Patel, D, Kellici, S and Saha, B (2014). Green Process Engineering as the Key to Future Processes. Processes. 2 (1), pp. 311-332.
Rapid synthesis of graphene quantum dots using a continuous hydrothermal flow synthesis approach
Kellici, S, Acord, J, Power, N, Morgan, D, Coppo, P, Heil, T and Saha, B (2017). Rapid synthesis of graphene quantum dots using a continuous hydrothermal flow synthesis approach. RSC Advances. 24, pp. 14716-14720. https://doi.org/10.1039/c7ra00127d
Selective Calixarene Directed Synthesis of MXene Plates, Crumpled Sheets, Spheres and Scrolls.
Vaughn, A, Ball, J, Heil, T, Morgan, D, Lampronti, G, Maršalkaitė, G, Raston, CL, Power, N and Kellici, S (2017). Selective Calixarene Directed Synthesis of MXene Plates, Crumpled Sheets, Spheres and Scrolls. Chemistry. 23 (34), pp. 8128-8133. https://doi.org/10.1002/chem.201701702
Greener synthesis of 1, 2 butylene carbonate from CO2 using graphene-inorganic nanocomposite catalysis
Onyenkeadi, V, Kellici, S and Saha, B (2017). Greener synthesis of 1, 2 butylene carbonate from CO2 using graphene-inorganic nanocomposite catalysis. SEEP 2017 –10th International Conference on Sustainable Energy & Environmental Protection. Bled, Slovenia 27 - 30 Jun 2017
Greener synthesis of styrene carbonate from CO2 using graphene-inorganic nanocomposite catalysts
Onyenkeadi, V, Kellici, S and Saha, B (2017). Greener synthesis of styrene carbonate from CO2 using graphene-inorganic nanocomposite catalysts. 10th World Congress of Chemical Engineering (WCCE10). Barcelona, Spain 01 - 05 Oct 2017
New Pathways in the Synthesis of 2-Dimensional Materials
Kellici, S (2017). New Pathways in the Synthesis of 2-Dimensional Materials. 1st Euro-Mediterranean Conference for Environmental Integration. Sousse, Tunisia 22 - 25 Nov 2017 Springer. https://doi.org/10.1007/978-3-319-70548-4_1
Imaging the continuous hydrothermal flow synthesis of nanoparticulate CeO2 at different supercritical water temperatures using in situ angle-dispersive diffraction
Middelkoop, V, Tighe, CJ, Kellici, S, Gruar, RI, Perkins, JM, Jacques, SDM, Barnes, P and Darr, JA (2014). Imaging the continuous hydrothermal flow synthesis of nanoparticulate CeO2 at different supercritical water temperatures using in situ angle-dispersive diffraction. Journal of Supercritical Fluids. 87, pp. 118 - 128. https://doi.org/10.1016/j.supflu.2013.12.022
Optical and photocatalytic behaviours of nanoparticles in the Ti-Zn-O binary system
Goodall, JBM, Kellici, S, Illsley, D, Lines, R, Knowles, JC and Darr, JA (2014). Optical and photocatalytic behaviours of nanoparticles in the Ti-Zn-O binary system. RSC Advances. 4 (60), pp. 31799 - 31809. https://doi.org/10.1039/c3ra48030e