Spray deposited copper zinc tin sulphide (Cu<inf>2</inf>ZnSnS<inf>4</inf>) film as a counter electrode in dye sensitized solar cells
Journal article
Swami, S.K., Chaturvedi, N., Kumar, A., Chander, N., Dutta, V., Kumar, D.K., Ivaturi, A., Senthilarasu, S. and Upadhyaya, H.M. (2014). Spray deposited copper zinc tin sulphide (Cu<inf>2</inf>ZnSnS<inf>4</inf>) film as a counter electrode in dye sensitized solar cells. Physical Chemistry Chemical Physics. 16 (43), pp. 23993-23999. https://doi.org/10.1039/c4cp03312d
| Authors | Swami, S.K., Chaturvedi, N., Kumar, A., Chander, N., Dutta, V., Kumar, D.K., Ivaturi, A., Senthilarasu, S. and Upadhyaya, H.M. |
|---|---|
| Abstract | Stoichiometric thin films of Cu2ZnSnS4 (CZTS) were deposited by the spray technique on a FTO coated glass substrate, with post-annealing in a H2S environment to improve the film properties. CZTS films were used as a counter electrode (CE) in Dye-Sensitized Solar Cells (DSCs) with N719 dye and an iodine electrolyte. The DSC of 0.25 cm2 area using a CE of CZTS film annealed in a H2S environment under AM 1.5G illumination (100 mW cm-2) exhibited a short circuit current density (JSC) = 18.63 mA cm-2, an open circuit voltage (VOC) = 0.65 V and a fill factor (FF) = 0.53, resulting in an overall power conversion efficiency (PCE) = 6.4%. While the DSC using as deposited CZTS film as a CE showed the PCE = 3.7% with JSC = 13.38 mA cm-2, VOC = 0.57 V and FF = 0.48. Thus, the spray deposited CZTS films can play an important role as a CE in the large area DSC fabrication. © the Partner Organisations 2014. |
| Keywords | CZTS; Spray Process; Sulphurisation; Dye Sensitized Solar Cell |
| Year | 2014 |
| Journal | Physical Chemistry Chemical Physics |
| Journal citation | 16 (43), pp. 23993-23999 |
| Publisher | Royal Society of Chemistry (RSC) |
| ISSN | 1463-9076 |
| Digital Object Identifier (DOI) | https://doi.org/10.1039/c4cp03312d |
| Publication dates | |
| 15 Oct 2014 | |
| Online | 06 Oct 2014 |
| Publication process dates | |
| Accepted | 29 Sep 2014 |
| Deposited | 02 Feb 2021 |
| Accepted author manuscript | License File Access Level Open |
Permalink -
https://openresearch.lsbu.ac.uk/item/8vyy2
Download files
Accepted author manuscript
| Spray deposited copper zinc tin sulphide (Cu 2 ZnSnS 4) film as a counter electrode in dye sensitized solar cells.doc | ||
| License: CC BY 4.0 | ||
| File access level: Open | ||
108
total views225
total downloads0
views this month1
downloads this month
Export as
Related outputs
Graphene-like Dispersion and Strong Optical Absorption in Two-Dimensional RP-type Sr3Ti2S7 Perovskite
Liu, H., Gao, R., Yang, J., Banthia, R.D., Yang, F., Wang, T., Upadhyaya, H. and Jain, S. (2023). Graphene-like Dispersion and Strong Optical Absorption in Two-Dimensional RP-type Sr3Ti2S7 Perovskite. Crystal Growth & Design. 23 (12), pp. 8575-8583. https://doi.org/10.1021/acs.cgd.3c00608Tin Sulfide (SnS) Films Deposited by an Electric Field-Assisted Continuous Spray Pyrolysis Technique with Application as Counter Electrodes in Dye-Sensitized Solar Cells
Mohammad, T., Alam, F., Sadhanala, A., Upadhyaya, H.M. and Dutta, Viresh (2022). Tin Sulfide (SnS) Films Deposited by an Electric Field-Assisted Continuous Spray Pyrolysis Technique with Application as Counter Electrodes in Dye-Sensitized Solar Cells. ACS Omega. 7 (44), p. 39690–39696. https://doi.org/10.1021/acsomega.2c03454Implementing Supervised and Unsupervised Deep-Learning Methods to Predict Sputtering Plasma Features, a Step toward Digitizing Sputter Deposition of Thin Films
Salimian, A., Pardo Sanchez, C., Hasnath, M., Haine, E. and Upadhyaya, H. (2022). Implementing Supervised and Unsupervised Deep-Learning Methods to Predict Sputtering Plasma Features, a Step toward Digitizing Sputter Deposition of Thin Films. Coatings. 12 (7), p. 953. https://doi.org/10.3390/coatings12070953Thermal spray coatings for electromagnetic wave absorption and interference shielding: a review and future challenges
Faisal, N.H., Ahmed, R., Sellami, N., Prathuru, A., Njuguna, J., Venturi, F., Hussain, T., Nezhad, H.Y., Kumar, N., Goel, S., Upadhyaya, H., Joshi, S., Muhammad-Sukki, F., Prabhu, R., Mallick, T., Whittow, W. and Kamnis, S. (2022). Thermal spray coatings for electromagnetic wave absorption and interference shielding: a review and future challenges. Advanced Engineering Materials. https://doi.org/10.1002/adem.202200171Artificial Neural Networks to Predict Sheet Resistance of Indium-Doped Zinc Oxide Thin Films Deposited via Plasma Deposition
Salimian, A., Aminishahsavarani, A. and Upadhyaya, H. (2022). Artificial Neural Networks to Predict Sheet Resistance of Indium-Doped Zinc Oxide Thin Films Deposited via Plasma Deposition. Coatings. 12 (2), p. 225. https://doi.org/10.3390/coatings12020225A Bibliometric Study on Biomimetic and Bioinspired Membranes for Water Filtration
Goel, G., Hélix-Nielsen, C., Upadhyaya, H. and Goel, S. (2021). A Bibliometric Study on Biomimetic and Bioinspired Membranes for Water Filtration . npj Clean Water. 4. https://doi.org/10.1038/s41545-021-00131-4Large scale manufacturing route to metamaterial coatings using thermal spray techniques and their response to solar radiation
Faisal, N.H., Sellami, N., Venturi, F., Hussain, T., Mallick, T., Muhammad-Sukki, F., Bishop, A., Upadhyaya, H., Kumar, N. and Goel, S. (2021). Large scale manufacturing route to metamaterial coatings using thermal spray techniques and their response to solar radiation. Emergent Materials. https://doi.org/10.1007/s42247-021-00252-zAtomic scale friction studies on single crystal GaAs using AFM and molecular dynamics simulation
Fan, P., Goel, S., Luo, X. and Upadhyaya, H. (2021). Atomic scale friction studies on single crystal GaAs using AFM and molecular dynamics simulation. Nanomanufacturing and Metrology. https://doi.org/10.1007/s41871-021-00109-3Hypothesis on the Influence of the Magnetic Behaviour of Hydrogen Doped Zinc Oxide during Its Plasma Sputtering Process
Salimian, A., Hasnath, A., Aminishahsavarani, A. and Upadhyaya, H. (2021). Hypothesis on the Influence of the Magnetic Behaviour of Hydrogen Doped Zinc Oxide during Its Plasma Sputtering Process. Coatings. 11 (2), p. e222. https://doi.org/10.3390/coatings11020222Horizons of modern molecular dynamics simulation in digitalised solid freeform fabrication with advanced materials
Goel, S., Knaggs, M., Goel, G., Zhou, X. W., Upadhyaya, H.M., Thakur, V. F., Kumar, V., Bizarri, G., Tiwari, A., Murphy, A., Stukowskii, A. and Matthewsj, A. (2020). Horizons of modern molecular dynamics simulation in digitalised solid freeform fabrication with advanced materials. Materials Today Chemistry. 18, p. 100356. https://doi.org/10.1016/j.mtchem.2020.100356Phase evolution, morphological, optical and electrical properties of femtosecond pulsed laser deposited TiO2 thin films
Kumi-Barimah, E, Penhale-Jones, R, Salimian, A, Upadhyaya, H, Hasnath, A. and Jose, G (2020). Phase evolution, morphological, optical and electrical properties of femtosecond pulsed laser deposited TiO2 thin films. Scientific Reports. 10 (1). https://doi.org/10.1038/s41598-020-67367-xResilient and Agile Engineering Solutions to Address Societal Challenges like Coronavirus Pandemic
Goel, S., Hawi, S., Goel, G., Thakur, V.K., Pearce, O., Hoskins, C., Hussain, T., Agrawal, A., Upadhyaya, H., Cross, G. and Barber, A. (2020). Resilient and Agile Engineering Solutions to Address Societal Challenges like Coronavirus Pandemic. Materials Today Chemistry. https://doi.org/10.1016/j.mtchem.2020.100300Synthesis of SnSe quantum dots by successive ionic layer adsorption and reaction (SILAR) method for efficient solar cells applications
Kishore Kumar, D, Loskot, J, Kříž, J, Bennett, N, Upadhyaya, HM, Sadhu, V, Venkata Reddy, C and Reddy, KR (2020). Synthesis of SnSe quantum dots by successive ionic layer adsorption and reaction (SILAR) method for efficient solar cells applications. Solar Energy. 199, pp. 570-574. https://doi.org/10.1016/j.solener.2020.02.050Highly Conductive Zinc Oxide Based Transparent Conductive Oxide Films Prepared using RF Plasma Sputtering Under Reducing Atmosphere
Salimian, A., Upadhyaya, H., Hasnath, A., Aminishahsavarani, A., Pardo Sanchez, C., Anguilano, L., Uchechukwu O. and Sanchez, C (2020). Highly Conductive Zinc Oxide Based Transparent Conductive Oxide Films Prepared using RF Plasma Sputtering Under Reducing Atmosphere. Coatings. 10 (5), p. 472. https://doi.org/10.3390/coatings10050472Optical analysis of RF sputtering plasma through colour characterization
Salimian, A., Haghpanahan, R., Hasnath, A. and Upadhyaya, H. (2019). Optical analysis of RF sputtering plasma through colour characterization. Coatings. 9 (5), pp. 315-315. https://doi.org/10.3390/coatings9050315