Towards a mechanistic understanding of particle shrinkage during biomass pyrolysis via synchrotron X-ray microtomography and in-situ radiography
Journal article
Barr, M. R., Jervis, R., Zhang, Y., Bodey, A. J., Rau, C., Shearing, P. R., Brett, D. J. L., Titirici, M.-M. and Volpe, R. (2021). Towards a mechanistic understanding of particle shrinkage during biomass pyrolysis via synchrotron X-ray microtomography and in-situ radiography. Scientific Reports. 11, p. 2656. https://doi.org/10.1038/s41598-020-80228-x
| Authors | Barr, M. R., Jervis, R., Zhang, Y., Bodey, A. J., Rau, C., Shearing, P. R., Brett, D. J. L., Titirici, M.-M. and Volpe, R. |
|---|---|
| Abstract | Accurate modelling of particle shrinkage during biomass pyrolysis is key to the production of biochars with specific morphologies. Such biochars represent sustainable solutions to a variety of adsorption-dependent environmental remediation challenges. Modelling of particle shrinkage during biomass pyrolysis has heretofore been based solely on theory and ex-situ experimental data. Here we present the first in-situ phase-contrast X-ray imaging study of biomass pyrolysis. A novel reactor was developed to enable operando synchrotron radiography of fixed beds of pyrolysing biomass. Almond shell particles experienced more bulk shrinkage and less change in porosity than did walnut shell particles during pyrolysis, despite their similar composition. Alkaline pretreatment was found to reduce this difference in feedstock behaviour. Ex-situ synchrotron X-ray microtomography was performed to study the effects of pyrolysis on pore morphology. Pyrolysis led to a redistribution of pores away from particle surfaces, meaning newly formed surface area may be less accessible to adsorbates. |
| Keywords | Pyrolysis; Particle Shrinkage; In-Situ Imaging; Radiography; Tomography |
| Year | 2021 |
| Journal | Scientific Reports |
| Journal citation | 11, p. 2656 |
| Publisher | Nature Research |
| ISSN | 2045-2322 |
| Digital Object Identifier (DOI) | https://doi.org/10.1038/s41598-020-80228-x |
| Web address (URL) | https://www.nature.com/articles/s41598-020-80228-x |
| Publication dates | |
| Online | 29 Jan 2021 |
| Publication process dates | |
| Accepted | 16 Dec 2020 |
| Deposited | 17 Aug 2023 |
| Publisher's version | License File Access Level Open |
| Accepted author manuscript | License File Access Level Controlled |
Permalink -
https://openresearch.lsbu.ac.uk/item/94v75
Download files
Publisher's version
| Towards a mechanistic understanding of particle shrinkage during biomass pyrolysis via synchrotron X-ray microtomography and in-situ radiography.pdf | ||
| License: CC BY 4.0 | ||
| File access level: Open | ||
48
total views312
total downloads4
views this month202
downloads this month
Export as
Related outputs
Ionic Liquid Processing of Residual Wood Powder into Additive-Free Wood Composites
Barr, M.R. and Lee, K.Y. (2024). Ionic Liquid Processing of Residual Wood Powder into Additive-Free Wood Composites. Waste and Biomass Valorization. https://doi.org/10.1007/s12649-024-02586-1Biochar-based wastewater treatment to combat antimicrobial resistance
Fady, P.-E., Richardson, A. K., Barron, L. P., Mason, A. J., Volpe, R. and Barr, M. R. (2022). Biochar-based wastewater treatment to combat antimicrobial resistance. XII Iberoamerican Congress on Pulp and Paper Research. Girona, Spain 28 Jun - 01 Jul 2022 https://doi.org/10256/21215Producing cellulose-reinforced biocomposite films from biomass using ionic liquids
Barr, M. and Lee, K.-Y. (2022). Producing cellulose-reinforced biocomposite films from biomass using ionic liquids. XII Iberoamerican Congress on Pulp and Paper Research. Girona, Spain 28 Jun - 01 Jul 2022 University of Girona. https://doi.org//10256/21215
Alkaline pretreatment of walnut shells increases pore surface hydrophilicity of derived biochars
Barr, M. R., Forster, L., D’Agostino, C. and Volpe, R. (2022). Alkaline pretreatment of walnut shells increases pore surface hydrophilicity of derived biochars. Applied Surface Science. 571, p. 151253. https://doi.org/10.1016/j.apsusc.2021.151253Identifying Synergistic Effects between Biomass Components during Pyrolysis and Pointers Concerning Experiment Design
Barr, M. R., Volpe, R. and Kandiyoti, R. (2021). Identifying Synergistic Effects between Biomass Components during Pyrolysis and Pointers Concerning Experiment Design. ACS Sustainable Chemistry & Engineering. 9 (16), p. 5603–5612. https://doi.org/10.1021/acssuschemeng.1c00051Liquid biofuels from food crops in transportation – A balance sheet of outcomes
Barr, M. R., Volpe, R. and Kandiyoti, R. (2021). Liquid biofuels from food crops in transportation – A balance sheet of outcomes. Chemical Engineering Science: X. 10, p. 100090. https://doi.org/10.1016/j.cesx.2021.100090X-Ray Image Analysis Code
Barr, M. R. (2020). X-Ray Image Analysis Code. OpenAIRE. https://doi.org/10.5281/zenodo.3742013Characterization of aggregate behaviors of torrefied biomass as a function of reaction severity
Barr, M., Kung, K. S., Thengane, S. K., Mohan, V., Sweeney, D. and Ghoniem, A. F. (2020). Characterization of aggregate behaviors of torrefied biomass as a function of reaction severity. Fuel. 266, p. 117152. https://doi.org/10.1016/j.fuel.2020.117152Reactivity of cellulose during hydrothermal carbonization of lignocellulosic biomass.
Volpe, M., Messineo, A., Makela, M., Barr, M. R., Volpe, R., Corrado, C. and Fiori, L. (2020). Reactivity of cellulose during hydrothermal carbonization of lignocellulosic biomass. Fuel Processing Technology. 206, p. 106456. https://doi.org/10.1016/j.fuproc.2020.106456On the suitability of thermogravimetric balances for the study of biomass pyrolysis
Barr, M., Volpe, M., Messineo, A. and Volpe, R. (2020). On the suitability of thermogravimetric balances for the study of biomass pyrolysis. Fuel. 276, p. 118069. https://doi.org/10.1016/j.fuel.2020.118069Towards resolving mechanisms of particle shrinking during biomass pyrolysis via micro-computed tomography and in-situ radiography
Barr, M. R., Zhang Y., Jervis R., Bodey A., Rau C. and Volpe R. (2019). Towards resolving mechanisms of particle shrinking during biomass pyrolysis via micro-computed tomography and in-situ radiography. Centre of Advanced Materials for Integrated Energy Systems Workshop: Multi-Modal Characterisation of Energy Materials . Cambridge, UK 06 Nov 2019Study of char morphology during biomass pyrolysis and gasification via micro-computed tomography
Barr, M. R., Zhang, Y., Jervis, R. and Volpe, R. (2019). Study of char morphology during biomass pyrolysis and gasification via micro-computed tomography. American Chemical Society Fall 2019 National Meeting & Exposition. San Diego, CA, USA 25 - 29 Aug 2019Influence of Reactor Design on Product Distributions from Biomass Pyrolysis
Barr, M., Volpe, R. and Kandiyoti, R. (2019). Influence of Reactor Design on Product Distributions from Biomass Pyrolysis. ACS Sustainable Chemistry & Engineering. 7 (16), p. 13734–13745. https://doi.org/10.1021/acssuschemeng.9b01368