Identifying Raman modes of Sb2Se3 and their symmetries using angle-resolved polarised Raman spectra

Journal article

Fleck, N., Hobson, T. D. C., Savory, C. N., Buckeridge, J., Veal, T. D., Correia, M. R., Scanlon, D., Durose, K. and Jäckel, F. (2020). Identifying Raman modes of Sb2Se3 and their symmetries using angle-resolved polarised Raman spectra. Journal of Materials Chemistry A. 8, pp. 8337-8344. https://doi.org/10.1039/D0TA01783C
AuthorsFleck, N., Hobson, T. D. C., Savory, C. N., Buckeridge, J., Veal, T. D., Correia, M. R., Scanlon, D., Durose, K. and Jäckel, F.
Abstract

The physical properties of antimony selenide (Sb2Se3) are highly anisotropic. Angle-resolved polarised Raman spectroscopy was employed to characterise oriented crystals and used in conjunction with group theory structural analysis to assign vibrational symmetries to the peaks observed in the Raman spectra. The phonon energies were corroborated via density functional theory (DFT) calculations. Furthermore, a straightforward method is proposed to verify the desirable (001) plane orientation of film growth for device applications via minimisation of the 155 cm−1 peak in the Raman spectrum.

Year2020
JournalJournal of Materials Chemistry A
Journal citation8, pp. 8337-8344
PublisherRoyal Society of Chemistry (RSC)
Digital Object Identifier (DOI)https://doi.org/10.1039/D0TA01783C
Web address (URL)https://pubs.rsc.org/en/content/articlelanding/2020/TA/D0TA01783C
Publication dates
Print15 Apr 2020
Publication process dates
Accepted08 Apr 2020
Deposited10 Jan 2022
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Buckeridge et al. Reply:
Buckeridge, J., Catlow, C. R. A., Scanlon, D. O., Keal, T. W., Sherwood, P., Miskufova, M., Walsh, A., Woodley, S. M. and Sokol, A. A. (2015). Buckeridge et al. Reply: Physical Review Letters. 115 (2), p. 029702. https://doi.org/10.1103/PhysRevLett.115.029702
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